Specific Polymers
Prestataire R&D privé Accréditation CIR
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Téléphone : (+33) (0)4 67 59 30 25
Mail : cedric.loubat [ at ] specificpolymers.fr
Adresse :
Avenue de l'Europe
CAP ALPHA
34830 Clapiers
France
Web : www.specificpolymers.fr
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Description
(Extrait du site web) |
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SPECIFIC POLYMERS est une société spécialisée dans la mise au point et dans la production de composés chimiques innovants.
La vocation de SPECIFIC POLYMERS s'inscrit dans le développement de produits macromoléculaires de type amorceur, monomère et oligomère destinés aux industries de haute technologie liées au domaine des polymères de spécialités : Polymères Fluorés, Polymères Siliciés et Polymères Phosphorés Une étroite collaboration normalisée par un contrat d'incubation lie SPECIFIC POLYMERS l'Ecole Nationale Supérieure de Chimie de Montpellier ENSCM et le Laboratoire de Chimie Macromoléculaire LCM (Pr B. Boutevin / UMR CNRS 5076) et lui permet ainsi de bénéficier d'un environnement scientifique et technologique de premier plan (Pilote industriel PROKHEMIA). SPECIFIC POLYMERS, lauréat du concours 2001 d'Aides à la Création d'Entreprises de Technologies Innovantes est soutenu par l'ensemble du réseau régional voué à ce type d'entreprise; Centre Européen d'Entreprise et d'Innovation CEEI CAP ALPHA et Languedoc Roussillon Incubation LRI (Montpellier 34). |
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Profil scientifique partiel |
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Domaines étudiés partiels
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Domaines scientifiques
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Chimie
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Quelques documents de Specific Polymers
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New fluorinated surfactants based on vinylidene fluoride telomers
Auteurs :
Bruno Ameduri, Bernard Boutevin, Gilles Boutevin, Cedric Loubat et Dominique Tiffes
Masquer le résumé
The synthesis of CnF2n+1(VDF)x-(CH2)p- where n = 2, 4; x = 2, 3, 4; p = 0, 1, 2 and VDF and stand for vinylidene fluoride (VDF) and I, OH, or CO2H, respectively, are presented. First, the radical telomerization of VDF with CnF2n+1-I to direct low molecular weight-telomers was investigated in various experimental conditions: initiators, temperatures and solvents to favour the formation of CnF2n+1(VDF)xI. Whatever the experimental conditions, it was observed the regioselective radical addition of CnF2n+1 radical onto the methylene site of VDF. Then, ethylenation of these VDF telomers was achieved in the presence of peroxy initiator with a quantitative conversion of the VDF-containing iodide reactants. Chemical change of RF(VDF)xC2H4I into RF(VDF)C2H4OH occurred in two steps: (i) from a mixture of DMF/water (for which a 6/1 content led to the best conditions); (ii) followed by a basic medium to saponify RF(VDF)xCH2CH2OCOH formiate into the corresponding VDF-containing alcohols. Suitable conditions were found to avoid any dehydrofluorination of the VDF telomeric chain. Oxidation of these fluorinated alcohols in the presence of H2SO4/CrO3 mixture led to the corresponding CnF2n+1(VDF)xCH2CO2H carboxylic acids. Surface tensions of these VDF-containing carboxylic acids were achieved reaching a value of 19.8 mN m-1 for a surfactant concentration of 5 g L-1, showing similar values as that of commercially available perfluorooctanoic acid (PFOA) while critical micellar concentration value of C2F5CH2CF2CH2CF2CH2CO2H was 1.4 g L-1 at room temperature.
Keywords :
Fluorinated alcohol ; Fluorinated carboxylic acid ; Fluorinated surfactant ; Telomerization ; Vinylidene fluoride
Source :
HAL
New fluorinated surfactants based on vinylidene fluoride telomers
Auteurs :
Bruno Ameduri, Bernard Boutevin, Gilles Boutevin, Cedric Loubat et Dominique Tiffes
Masquer le résumé
The synthesis of CnF2n+1(VDF)x-(CH2)p- where n = 2, 4; x = 2, 3, 4; p = 0, 1, 2 and VDF and stand for vinylidene fluoride (VDF) and I, OH, or CO2H, respectively, are presented. First, the radical telomerization of VDF with CnF2n+1-I to direct low molecular weight-telomers was investigated in various experimental conditions: initiators, temperatures and solvents to favour the formation of CnF2n+1(VDF)xI. Whatever the experimental conditions, it was observed the regioselective radical addition of CnF2n+1 radical onto the methylene site of VDF. Then, ethylenation of these VDF telomers was achieved in the presence of peroxy initiator with a quantitative conversion of the VDF-containing iodide reactants. Chemical change of RF(VDF)xC2H4I into RF(VDF)C2H4OH occurred in two steps: (i) from a mixture of DMF/water (for which a 6/1 content led to the best conditions); (ii) followed by a basic medium to saponify RF(VDF)xCH2CH2OCOH formiate into the corresponding VDF-containing alcohols. Suitable conditions were found to avoid any dehydrofluorination of the VDF telomeric chain. Oxidation of these fluorinated alcohols in the presence of H2SO4/CrO3 mixture led to the corresponding CnF2n+1(VDF)xCH2CO2H carboxylic acids. Surface tensions of these VDF-containing carboxylic acids were achieved reaching a value of 19.8 mN m-1 for a surfactant concentration of 5 g L-1, showing similar values as that of commercially available perfluorooctanoic acid (PFOA) while critical micellar concentration value of C2F5CH2CF2CH2CF2CH2CO2H was 1.4 g L-1 at room temperature.
Keywords :
Fluorinated alcohol ; Fluorinated carboxylic acid ; Fluorinated surfactant ; Telomerization ; Vinylidene fluoride
Source :
HAL
Physically-Crosslinked Fluorosilicone Elastomers Obtained by Self-Assembly and Template Polyconden-sation of Tailored Building Blocks
Auteurs :
Sébastien Andre, Gilles Boutevin, Bernard Boutevin, Brigitte Descamps, Francois Ganachaud, F. Guida-Pietrasanta, Christine Joly-Duhamel, Claire Longuet, Michel Ramonda et A. Ratsimihety
Pas de résumé disponible
Source :
HAL
NanoMembranes against Global Warming
NANOGLOWA Sujets :
Materials Technology, Industrial Manufacture
Type de contrat :
Integrated Project
Participants :
KEMA NEDERLAND BV NEDERLAND
KEMA NEDERLAND BV
KEMA POWER GENERATION AND SUSTAINABLES PO Box 9035 Utrechtseweg 310 NEDERLAND
PAUL SCHERRER INSTITUT SCHWEIZ/SUISSE/SVIZZERA
PAUL SCHERRER INSTITUT
DEPARTMENT GENERAL ENERGY (ENE), ELECTROCHEMISTRY LAB. (ECL) Villigen SCHWEIZ/SUISSE/SVIZZERA
LASER ZENTRUM HANNOVER E.V. DEUTSCHLAND
LASER ZENTRUM HANNOVER E.V.
LASER ZENTRUM HANNOVER E.V. Hollerithallee 8 DEUTSCHLAND
YODFAT ENGINEERS (1994) LTD ISRAEL
YODFAT ENGINEERS (1994) LTD
YODFA ENGINEERS (1994) LTD Moshav Yodfat ISRAEL
NORGES TEKNISK - NATURVITENSKAPELIGE UNIVERSITET NORGE
NORGES TEKNISK - NATURVITENSKAPELIGE UNIVERSITET
FACULTY OF SCIENCE AND TECHNOLOGY Hoegskoleringen 1 NORGE
UNIVERSITEIT TWENTE NEDERLAND
UNIVERSITEIT TWENTE
DEPARTMENT OF SCIENCE AND TECHNOLOGY,MEMBRANE TECHNOLOGY GROUP PO Box 217 DRIENERLOLAAN 5 NEDERLAND
HYGEAR B.V. NEDERLAND
HYGEAR B.V.
HYGEAR PO Box 5280 Westervoortsedijk 73 NEDERLAND
INASCO - INTEGRATED AEROSPACE SCIENCES CORPORATION O.E. HELLAS
INASCO - INTEGRATED AEROSPACE SCIENCES CORPORATION O.E.
RTD Miaouli St., 22 HELLAS
PARKER FILTRATION AND SEPARATION B.V. NEDERLAND
PARKER FILTRATION AND SEPARATION B.V.
7002 MEMBRANE MODULE DEVELOPMENT PO Box 258 Oude Kerkstraat 4 NEDERLAND
DONG ENERGY GENERATION A/S DANMARK
DONG ENERGY GENERATION A/S
CHEMISTRY & MATERIALS Kraftværksvej 53, Skærbæk DANMARK
FACULTES UNIVERSITAIRES NOTRE-DAME DE LA PAIX DE NAMUR BELGIQUE-BELGIË
FACULTES UNIVERSITAIRES NOTRE-DAME DE LA PAIX DE NAMUR
CHEMISTRY DEPARTMENT / NUCLEAR MAGNETIC RESONANCE LABORATORY Rue de Bruxelles, 61 BELGIQUE-BELGIË
CONSIGLIO NAZIONALE DELLE RICERCHE ITALIA
CONSIGLIO NAZIONALE DELLE RICERCHE
RESEARCH INSTITUTE ON MEMBRANE TECHNOLOGY, ITM-CNR Piazzale Aldo Moro, 7 ITALIA
HAFFMANS BV NEDERLAND
HAFFMANS BV
RESEARCH & DEVELOPMENT PO Box 3150 Marinus Dammeweg 30 NEDERLAND
SPECIFIC POLYMERS SARL FRANCE
SPECIFIC POLYMERS SARL
SPECIFIC POLYMERS 8, Rue de l'Ecole Normale FRANCE
INSTALACIONES INABENSA SA ESPAÑA
INSTALACIONES INABENSA SA
R&D DEPARTMENT Manuel Velasco Pando 7 ESPAÑA
REPSOL YPF, S.A. ESPAÑA
REPSOL YPF, S.A.
DIRECCION DE TECHNOLOGIA QUIMICA. COORDINACION DE POLIETILENO. Paseo de la Castellana 278 ESPAÑA
ENDESA GENERACION SA ESPAÑA
ENDESA GENERACION SA
RESEARCH AND DEVELOPMENT UNIT Avenida de la Borbolla, 5 ESPAÑA
SIEMENS AG DEUTSCHLAND
SIEMENS AG
SIEMENS AG POWER GENERATION, DEPT. PG CTET4 Postfach 3220 WITTELSBACHERPLATZ 21 DEUTSCHLAND
INSTYTUT CHEMII PRZEMYSLOWEJ IM. PROF. IGNACEGO MOSCICKIEGO POLSKA
INSTYTUT CHEMII PRZEMYSLOWEJ IM. PROF. IGNACEGO MOSCICKIEGO
DEPARTMENT FOR SEPARATION AND PURIFICATION OF CHEMICAL COMPOUNDS ul. Rydygiera 8 POLSKA
E.ON ENGINEERING GMBH DEUTSCHLAND
E.ON ENGINEERING GMBH
E.ON ENGINEERING Bergmannglueckstrasse 41-43 DEUTSCHLAND
RHEINISCH-WESTFALISCHE TECHNISCHE HOCHSCHULE AACHEN DEUTSCHLAND
RHEINISCH-WESTFALISCHE TECHNISCHE HOCHSCHULE AACHEN
CHEMICAL ENGINEERING DEPARTMENT Templergraben 55 DEUTSCHLAND
ECOLE NATIONALE SUPERIEURE DE CHIMIE DE MONTPELLIER FRANCE
ECOLE NATIONALE SUPERIEURE DE CHIMIE DE MONTPELLIER
IEM 8 Rue de l'Ecole Normale FRANCE
DONG ENERGY GENERATION Denmark
DONG ENERGY GENERATION
PROJECT & ENGINEERING Kraftvaerksvey 53 Denmark
CERAMIQUES TECHNIQUES ET INDUSTRIELLES France
CERAMIQUES TECHNIQUES ET INDUSTRIELLES
Route de Saint-Privat - La Resclause France
ORELISS France
ORELISS
5 Chemin du Pilon France
INASCO - INTEGRATED AEROSPACE SCIENCES CORPORATION OE Greece
INASCO - INTEGRATED AEROSPACE SCIENCES CORPORATION OE
RTD Miaouli St., 22 Greece
EON ENGINEERING Germany
EON ENGINEERING
Bergmannsglückstr. 41-43 Germany
Siemens Germany
Siemens
Frauenauracherstr. 80 Germany
ISRAEL ELECTRIC CORPORATION LIMITED Israel
ISRAEL ELECTRIC CORPORATION LIMITED
MECHANICAL SYSTEM DESIGN DEPARTMENT, ENGINEERING DIVISION 1 Netiv Haor Street Israel
EDP GESTAO DA PRODUCAO DE ENERGIA Portugal
EDP GESTAO DA PRODUCAO DE ENERGIA
EDP - GESTÃO DA PRODUÇÃO DE ENERGIA, S.A. Avenida Jose Malhoa, Lote A-13 Portugal
ENDESA GENERACION Spain
ENDESA GENERACION
DIRECTORATE OF NUCLEAR PRODUCTION Principe de Vergara 187 Spain
INSTALACIONES INABENSA Spain
INSTALACIONES INABENSA
Manuel Velasco Pando, n. 7 Spain
REPSOL YPF Spain
REPSOL YPF
Paseo de la Castellana, 278-280 Spain
HAFFMANS Netherlands
HAFFMANS
RESEARCH & DEVELOPMENT PO Box Marinus Dammeweg 30 Netherlands
HYGEAR Netherlands
HYGEAR
HYGEAR PO Box Westervoortsedijk 73 Netherlands
KEMA NEDERLAND Netherlands
KEMA NEDERLAND
PO Box Utrechtseweg 310 Netherlands
PARKER FILTRATION AND SEPARATION Netherlands
PARKER FILTRATION AND SEPARATION
MEMBRANE MODULE DEVELOPMENT PO Box 258 Oude Kerkstraat 4 Netherlands
C TECH INNOVATION United Kingdom
C TECH INNOVATION
CAPENHURST TECHNOLOGY PARK Capenhurst Technology Park United Kingdom
The ultimate way to reduce CO2 emissions as required by the Kyoto protocol from the main contributors, the fossil fired power stations, is by CO2 capture. Existing methods (adsorption, non selective cooling) are not very cost- and energy effective: up to 25% consumption of the produced energy. CO2 separation through membranes will consume much less energy (8%), but suitable, reliable and economical membranes are currently non-existing. The objective is to develop optimal nanostructured membranes and installations for CO2 capture from power plants below 20 euro/ton with a build-in, smart, diagnostic technique. The consortium of 26 partners including 7 SMEs involves 14 countries. Five innovative membrane materials will be developed simultaneously.The project organisation will stimulate cross-fertilisation for achieving major breakthroughs. For this an integration, modelling and a diagnostics task is included and cooperation with and field-testing by 6 future end-users will guarantee the realistic outcome of the material research. The cost price for the membranes will be a factor 5 lower by increasing the performance through radical innovations in membrane technology: a spin-coated sub-micron layer, oriented nano-spurs with active groups through the layer of the membrane and inherent oxygen stability by the introduction of active groups as block-copolymers in the membrane backbone. Smart design modules, for long life, low degradation and contamination combined with integrated performance monitoring, will be developed and tested in the laboratory and in the field.Dissemination and exploitation strategies are incorporated in this project by including the mayor EU electricity companies and their equipment suppliers. Training activities and workshop s on membrane development and production, emission reduction and future sustainable power plant design for low CO2 emission are scheduled.
Source :
cordis
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